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9. 13.12 Lipsticks and glosses
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Lipstick
In general, lipsticks are composed of variable
proportions of the following ingredients
(in parts by weight):
| 15-30 |
Plant and mineral waxes |
| 3-8 |
Beeswax |
| 2-5 |
Fatty alcohols (C16-C18) |
| 5-10 |
Liquid, branched chain alcohols/esters |
| 15-30 |
Mineral oil (white petrolatum) |
| 5-10 |
Rosin methyl ester |
| 1-3 |
Honey |
| q.s. |
Perfume |
| q.s. |
Antioxidant |
| q.s. |
Sunscreen (micronized Ti02) |
| q.s. to 100 |
Castor oil |
are base formulations for lipsticks:
|
Ingredients
|
F1
(in parts by weight)
|
F2
(in parts by weight)
|
F3
(in parts by weight)
|
Beeswax
Carnauba wax
Candelille wax
Ozocerite
Lanolin
Acetylated lanolin
Lanolin alcohols ricinoleate
Isopropyl lanolate
Lanolin alcohols ethers (2 OP)
Lanolin alcohols
Cetyl alcohol
Isopropyl palmitate
Miristyl lactate
Castor oil
Pigments
Perfume
Antiodisants and preservative |
15
10
-
-
5
-
-
-
-
-
5
-
-
65
q.s.
q.s.
q.s.
|
10
3
8
4
-
-
5
10
-
5
-
-
-
55
q.s.
q.s.
q.s.
|
6
3
7
5
-
5
-
-
5
-
-
25
5
28
11
q.s.
q.s.
|
The waxes, alcohols and oil are mixed together
one after the other into the melted beeswax,
at a temperature of about 700C. Depending on the pigments and antioxidants
used, they' can be added at this stage (hot)
or once the mix has cooled. The pigments
may have to be premixed in the castor oil.
Pe~mes are added at approximately 400C or before the mass becomes too viscous.
The final mix is poured into forms, or extruded
for large scale production.
Lipstick
|
Ingredients
|
Lipstick
(parts by weight)
|
Lucid lipstick
(parts by weight)
|
Beeswax
Carnauba wax
Candelilla wax
Cacao butter
Hydrogenated lanolin
Ricinus oil
Sweeteners and aromas |
7.5
12.5
2.5
15
12
50
0.5
|
7
8
5
10
30
39.5
0.5
|
Both formulations are after Proserpio (1981).
If the sweetener is honey, its quantity should
be increased. Melt the ingredients and mix
them well. Pour into forms before hardening.
This is a more protective type of lipstick
(rather than a fashion, coloured one) but
some pigments or a Uvfilter can be added.
Simple lipstick
Ingredients (in parts by weight) modified
from Brown (1981):
| 3 |
Beeswax |
6 |
White petrolatum (Vaseline) |
| 6 |
Ceresin |
2 |
Liquid paraffin |
| 1 |
Lanolin |
1 |
Cetyl alcohol |
| 2 |
Pigments* |
q.s. |
Essential oila* |
|
|
q.s. |
Honey* |
* optional
Prepare moulds of small diameter, similar
to wax candles, using plastic tubing, PVC
or metal pipes and metal foil tubes. Clean
plastic syringes of the right diameter work
very well. Leave the plunger, but the tip
of the syringe should be cut off. The plunger
will also help in removing the stick.
Melt the wax and stir in the other products.
If so desired, pigments can be predispersed
in the liquid paraffin and essential oils
and honey should only be added below 500C. Pour into the moulds when almost cool.
Once hardened, place into the lipstick holders
and pass the tip quickly through a low flame
to give it a glossy finish.
Protective lipstick
Ingredients (in parts by weight) after Proserpio
(1981):
| 25 |
Beeswax |
| 5 |
Cetyl alcohol |
| 30 |
Oleic alcohol |
| 25 |
Mineral or ricinus (castor) oil |
| 15 |
Paraffin |
| q.s. |
Aromatic oils and sweetener (honey) |
Heat wax in a water bath (70 75°C)
add other ingredients and mix well. Before
hardening, add aromatic oil and pour into
forms. Sweetner can be honey and, for some
applications, a UVfilter and some pigments
can be added as well.
Moisturizing lipstick
Ingredients (in parts by weight) after Cosmetics
and Toiletries (1992):
| A) |
14 |
Lanolin (an hydrous Lanolin P95) |
|
5 |
Lanolin oil (Argonol 50) |
|
40 |
Mineral oil |
|
6 |
Cetyl alcohol |
|
2 |
Ozocerite |
|
8 |
Candelilla wax |
|
q.s. |
Preservative |
- Pigments dispersed in castor oil:
|
|
10 |
Titanium oxide |
|
8 |
Mica (and) titanium dioxide (Timica Pearl
White) |
|
6 |
D&C red 6 barium lake |
| C) |
q.s. |
Fragrance/flavour |
Heat the ingredients listed under A and mix
until clear. Add premixed B and mix well.
Adjust the temperature to 600C and add C. Pour into moulds. This formulation
makes an elegant glossy lipstick, which spreads
easily and conditions the lips.
Anhydrous (waterless) lip ointment
Ingredients (in parts by weight):
| 2-5 |
Beeswax |
| 2-5 |
Hydrogenated castor oil |
| 10-20 |
Polydecene |
| 20-40 |
PEG 22 dodecylglycol copolymer |
| 5-10 |
Mineral oil (white petrolatum) |
| 5-15 |
Honey |
| q.s. |
Sunscreen |
| q.s. |
Fragrance |
| q.s. to 100 |
POE 20 castor oil |
Mix like any other ointment.
Lucid lip ointment
Ingredients (in parts by weight) after Proserpio
(1981):
| 5 |
Beeswax |
10 |
Hydrogenated lanolin |
| 10 |
Honey |
5 |
Hydrogenated ricinus oil |
| 60 |
Ricinus oil |
q.s. |
Fragrances |
| 10 |
Cacao butter |
|
|
Mix like other ointments in section 9.13.3.
A very simple lip gloss can be made by melting
12 parts of cocoa butter with 1 part beeswax
(Krochmal, 1973).
Tinted lip gloss
Ingredients (in parts by volume) after Krochmal
(1973):
| 12 |
Beeswax |
| 24 |
Almond oil |
| 0.25 |
Carmine |
| 0.05 |
Oil of rose |
Melt the wax over a low heat in a water bath
and stir in the carmine. Gradually add the
almond oil and the oil of rose
9.13.13 Depilatory waxes
Depilatory waxes are made using various proportions
of resins, beeswax and oils. To obtain a
low melting point near 40 to 45 0C, honey is sometimes included. No other
ingredients are essential for this mixture.
The liquified waxes are applied in a thin
film on the skin and covered with a strip
of muslin cloth pressed firmly to the skin.
When cooled, the skin is pulled taut and
the cloth strip is pulled against the direction
of hair growth.
A French patent describes aromatic oils and
resins added to beeswax as analgesics or
perfumes and triethanolamine as an emulsifier.
The final mixture is spread on a siliconized
paper. According to Anon (1965) it consists
of the following (in parts by weight):
| 20 |
Beeswax |
1 |
Benzoin |
| 170 |
Resin |
0.5 |
Lemongrass oil |
| 90 |
Vegetable oil |
1 |
Butyl p-aminobenzoate |
| 10 |
Triethanolamine |
0.5 |
Jaborandi alcohol |
| 1 |
Tolu balsam |
|
|
Depilatory cream
Ingredients (in parts by volume):
| 42 |
Rosin |
| 37 |
Beeswax |
| 6 |
Carnauba wax |
| 15 |
Mineral oil (white petrolatum) |
| q.s. |
Preservatives, antioxidants and perfume |
Melt the beeswax and the carnauba wax and
mix in the resins and oil. When cooled to
below 400C add the other ingredients. If preservatives
and antioxidants are heat stable, they can
also be mixed earlier
9.13 14 Shaving preparations
Shaving cream (o/w)
Ingredients (in parts by volume) after Krochmal
(1973):
| 4 |
Stearic acid |
| 4 |
Mineral oil |
| 6 |
Beeswax |
| 4 |
Soap flakes |
| 16 |
Water (clean) |
Heat the water to 700C and dissolve the soap. Melt the stearic
acid and beeswax in a water bath to 75 0C and stir this into the soapy water Oand
emulsift. Stir and mix well. When homogeneous,
stir in the mineral oil. The mix might also
be scented with 0.1 part of an essential
oil.
After shave lotion
|
Ingredients
|
I
(parts by weight)
|
II
(parts by weight)
|
Ethanol (96% volume)
Sorbitol
Fragrance (aromatic oil)
Menthol
Methyl paraben (preservative)
Witch hazel extract
Propolis extract (10% EEP)
Water |
50
2.5
0.5
0.1
0.2
5
1
q.s. to 100
|
50
-
0.5
0.1
-
5
1
q.s. to 100
|
Dissolve all the ingredients completely in
the alcohol and dilute with the water, mixing
thoroughly. Leave to stand for 1 to 2 days
with adequate chilling or 1 week without
chilling, then filter to clear and bottle.
After shave cream (o/w)
Ingredients (in parts by weight):
| 3.0 |
Glyceryl monostearate |
| 0.5 |
Beeswax |
| 1.5 |
Stearyl alcohol |
| 2.5 |
Sorbitol |
| 2.5 |
Lapyrium chloride (Emcol 607 Witco) |
| 1.0 |
Steapyrium chloride (Emcol E 607 S Witco) |
| 0.1 |
Sodium benzoate |
| 0.3 |
Fragrances |
| q.s. to 100 |
Water |
Heat the first three ingredients together
to 70°C. In another vessel dissolve the next four
ingredients in water and heat to 70°C. Add
the oil phase to the aqueous phase with good
agitation and continue stirring while cooling.
Add the fragrances, at or below 40°C. Continue
stirring slowly until the mix reaches 25°C.
Bottle after 24 hours.
After shave gel
Ingredients (in parts by weight):
| 0.25 |
Carbomer 941 |
| q.s. to 100 |
Water |
| 2.0 |
Glycerol |
| 50.0 |
Ethyl alcohol |
| 2.5 |
TEA 10% aqueous |
| 0.1 |
Menthol |
| 0.1 |
Propolis extract (EEP) |
Under rapid stirring, slowly add the carbomer
resin to the water - glycerol mix. Continue
mixing until free of undispersed particles.
Dissolve menthol and propolis in alcohol.
Mix the two phases (aqueous and alcohol).
Add the TEA slowly, with good agitation.
For simpler production the resin and gel
agent may be replaced with locally available
gel forming substances (pectin or agar),
but compatibility with the alcohol has to
be tried first and different ratios tested.
The final consistency will be different.
Propolis content can be increased considerably.
3 Dr Luigi Rigano assisted in the preparation
of this Chapter with technical advice and
provision of formulations.
4Beeswax is completely non-allergenic, but
possible contamination with pollen may cause
allergic reactions in extremely sensitive
persons. Such effects are reduced or eliminated
by bleaching (almost all cosmetically used
beeswax is bleached) and otherwise freeing
beeswax from pollen by filtering.
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